Diastereoselective addition of metal-coordinated and 'naked' nucleophilic reagents to norephedrine derived 2-acyl-N-tosyl-oxazolidines

DOI: 10.1016/S0040-4020(96)01087-3

Source and publish data:

Tetrahedron p. 1759 - 1776 (1997)

Update date:2022-08-03

Topics:

Authors:

Poli, Giovanni

Maccagni, Elisa

Manzoni, Leonardo

Pilati, Tullio

Scolastico, Carlo

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Article abstract of DOI:10.1016/S0040-4020(96)01087-3

The addition of tri-s-butyl borohydrides to the 2-acetyl-1,3-oxazolidine 1 could be directed with high selectivity to either the Si or the Re π-carbonyl face under chelating or non-coordinating conditions respectively. Addition of hydrides to the correspo

Full text of DOI:10.1016/S0040-4020(96)01087-3

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