143768-87-0Relevant academic research and scientific papers
Bis(cyclopentadienyl)tetracarbonyldimolybdenum-alkyne Complexes Mediated Cycloaddition: the Formation of 3-Substituted Cyclopentenone Derivatives
Mukai, Chisato,Uchiyama, Masahiko,Hanaoka, Miyoji
, p. 1014 - 1015 (1992)
On heating, bis(cyclopentadienyl)tetracarbonyldimolybdenum-alkyne complexes undergo a cycloaddition with norbornadiene or norbornene to afford the corresponding 3-substituted cyclopentenone derivatives, which could hardly be obtained in the cobalt-complexed alkyne-mediated Pauson-Khand reaction.
Inhibition of enone reduction in aqueous-phase Pauson-Khand reactions
Krafft, Marie E.,Wright, James A.,Bo?aga, Llorente V. R.
, p. 71 - 74 (2007/10/03)
NMO-promoted room temperature cyclizations of the cobalt carbonyl complexes of substrates bearing terminal and internal alkynes gave exclusively the Pauson-Khand (PK) reaction adducts in a water-Triton X-100 medium.
