
Journal of the Chemical Society. Chemical communications p. 1014 - 1015 (1992)
Update date:2022-08-04
Topics:
Mukai, Chisato
Uchiyama, Masahiko
Hanaoka, Miyoji
On heating, bis(cyclopentadienyl)tetracarbonyldimolybdenum-alkyne complexes undergo a <2 + 2 + 1> cycloaddition with norbornadiene or norbornene to afford the corresponding 3-substituted cyclopentenone derivatives, which could hardly be obtained in the cobalt-complexed alkyne-mediated Pauson-Khand reaction.
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