Bis(cyclopentadienyl)tetracarbonyldimolybdenum-alkyne Complexes Mediated Cycloaddition: the Formation of 3-Substituted Cyclopentenone Derivatives

DOI: 10.1039/c39920001014

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1014 - 1015 (1992)

Update date:2022-08-04

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Authors:

Mukai, Chisato

Uchiyama, Masahiko

Hanaoka, Miyoji

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Article abstract of DOI:10.1039/c39920001014

On heating, bis(cyclopentadienyl)tetracarbonyldimolybdenum-alkyne complexes undergo a <2 + 2 + 1> cycloaddition with norbornadiene or norbornene to afford the corresponding 3-substituted cyclopentenone derivatives, which could hardly be obtained in the cobalt-complexed alkyne-mediated Pauson-Khand reaction.

Full text of DOI:10.1039/c39920001014

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