1437786-55-4

Upstream product

• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 479-27-6 naphthalene-1,8-diamine 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 1437786-68-9 (R)-2-(1,2-diphenylethyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 1437786-69-0 (S)-2-(1,2-diphenylethyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 1437786-65-6 C₂₉H₃₄B₂N₂O₂ 

Relevant academic research and scientific papers

A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes

Unsymmetric 1,1-diboryl alkenes bearing one -[BPin] (BPin = pinacolatoboryl) and one -[BDan] (BDan = 1,8-diaminonaphthalatoboryl) substituent each were hydrogenated in high yield and enantioselectivity using C1-symmetric pyridine(diimine) (PDI)

Regio- and enantioselective copper(I)-catalyzed hydroboration of borylalkenes: Asymmetric synthesis of 1,1-diborylalkanes

A bisphosphine/copper catalyst was used for the asymmetric hydroboration of 1,8-naphthalenediaminatoboryl (Bdan) substituted alkenes (see scheme; pin=pinacolato). Simple alkyl-substituted borylalkenes and styrene derivatives were hydroborated with high regio- and enantioselectivity. The electronic and steric properties of the Bdan group significantly affected the reactivity and regioselectivity of hydroboration.