1437786-68-9

Upstream product

• 591-50-4 iodobenzene 
• 1437786-55-4 (S)-2-(2-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 

Relevant academic research and scientific papers

Regio- and enantioselective copper(I)-catalyzed hydroboration of borylalkenes: Asymmetric synthesis of 1,1-diborylalkanes

A bisphosphine/copper catalyst was used for the asymmetric hydroboration of 1,8-naphthalenediaminatoboryl (Bdan) substituted alkenes (see scheme; pin=pinacolato). Simple alkyl-substituted borylalkenes and styrene derivatives were hydroborated with high regio- and enantioselectivity. The electronic and steric properties of the Bdan group significantly affected the reactivity and regioselectivity of hydroboration.