143839-00-3Relevant academic research and scientific papers
Electrooxidative Functionalizations of Dehydroabietic Acid
Uneyama, Kenji,Katayama, Tatsuo,Torii, Sigeru
, p. 3043 - 3044 (1987)
Dehydroabietic acid methyl ester (1) was converted into 7-acetoxydehydroabietic acid methyl ester by direct electrooxidation in acetic acid and 7-oxodehydroabietic acid methyl ester by ruthenium dioxide-mediated oxidation.Non-Kolbe type electrodecarboxylation of 1 resulted in the introduction of a double bond into the ring A of 1.
REGIOSELECTIVE REACTIONS OF ABIETIC ACID METHYL ESTER
Escudero, Javier,Marquez, Cecilio,Rabanal, Rosa Ma,Valverde, S.
, p. 3167 - 3170 (2007/10/02)
Ozonolysis of abietic acid methyl ester 1 in the presence of mercuric acetate afforded the 13,14-seco-derivative in fair yield (50percent).Selenium dioxide oxidation of 1 in t-butanol gave 9-α-hydroxy-abietic acid methyl ester 6, dehydroabietic acid methyl ester 4 and its 7α-hydroxy-derivative 4b.
