Bulletin of the Chemical Society of Japan p. 3043 - 3044 (1987)
Update date:2022-08-04
Topics: Epoxidation Nitration Halogenation Hydroxylation Carboxylation
Uneyama, Kenji
Katayama, Tatsuo
Torii, Sigeru
Dehydroabietic acid methyl ester (1) was converted into 7-acetoxydehydroabietic acid methyl ester by direct electrooxidation in acetic acid and 7-oxodehydroabietic acid methyl ester by ruthenium dioxide-mediated oxidation.Non-Kolbe type electrodecarboxylation of 1 resulted in the introduction of a double bond into the ring A of 1.
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