Electrooxidative Functionalizations of Dehydroabietic Acid

DOI: 10.1246/bcsj.60.3043

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3043 - 3044 (1987)

Update date:2022-08-04

Topics: Epoxidation Nitration Halogenation Hydroxylation Carboxylation

Authors:

Uneyama, Kenji

Katayama, Tatsuo

Torii, Sigeru

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Article abstract of DOI:10.1246/bcsj.60.3043

Dehydroabietic acid methyl ester (1) was converted into 7-acetoxydehydroabietic acid methyl ester by direct electrooxidation in acetic acid and 7-oxodehydroabietic acid methyl ester by ruthenium dioxide-mediated oxidation.Non-Kolbe type electrodecarboxylation of 1 resulted in the introduction of a double bond into the ring A of 1.

Full text of DOI:10.1246/bcsj.60.3043

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