1439401-65-6

Basic information

• Product Name: (E)-3-(2-bromophenyl)-N-methyl-N-phenylacrylamide
• Synonyms: (E)-3-(2-bromophenyl)-N-methyl-N-phenylacrylamide
• CAS NO: 1439401-65-6
• Molecular Weight: 316.197
• Mol File: 1439401-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-(2-bromophenyl)-N-methyl-N-phenylacrylamide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(2-bromophenyl)-N-methyl-N-phenylacrylamide(1439401-65-6)
• EPA Substance Registry System: (E)-3-(2-bromophenyl)-N-methyl-N-phenylacrylamide(1439401-65-6)

Safety Data

• Hazardous Substances Data: 1439401-65-6(Hazardous Substances Data)

Upstream product

• 7345-79-1 2-bromocinnamic acid 
• 100-61-8 N-methylaniline 

Downstream Products

• 1439401-86-1 3-(2-bromophenyl)-1-methylquinolin-2(1H)-one 

Relevant articles and documents

PhI(OCOCF3)2-mediated C-C bond formation concomitant with a 1,2-Aryl shift in a metal-free synthesis of 3-arylquinolin-2-ones

The reaction of the readily available N-methyl-N-phenylcinnamamides with phenyliodine bis(trifluoroacetate) (PIFA) in the presence of Lewis acids provides a general and efficient assembly of a variety of 3-arylquinolin-2-one compounds. This novel approach features not only metal-free oxidative C(sp 2)-C(sp2) bond formation but also an exclusive 1,2-aryl migration.