143977-91-7Relevant academic research and scientific papers
Highly practical boronic acid surrogates for the Suzuki-Miyaura cross-coupling
Bonin, Hélne,Leuma-Yona, Rodrigue,Marchiori, Bruno,Demonchaux, Patrice,Gras, Emmanuel
experimental part, p. 1132 - 1135 (2011/03/22)
Boronic acids and esters are well known substrates for the Suzuki-Miyaura cross-coupling. Yet their isolation can sometimes be tedious. We report here that the use of aryl dioxazaborocanes afford a simple isolation procedure while keeping a high efficienc
Base free aryl coupling of diazonium compounds and boronic esters: Self-activation allowing an overall highly practical process
Bonin, Helene,Delbrayelle, Dominique,Demonchaux, Patrice,Gras, Emmanuel
supporting information; experimental part, p. 2677 - 2679 (2010/07/08)
Boronic esters have long been considered as poor partners in cross-coupling reactions with arene diazoniums. Here is reported an unprecedented application of self-activated boronic esters in a base-free cross-coupling reaction with diazonium salts under mild and user friendly conditions.
