144080-51-3

Upstream product

• 144080-52-4 {(2,4,6-triisopropylphenyl)fluorostannyl}(supermesityl)phosphine 

Downstream Products

• 156420-57-4 C₃HOP[C₆H₂(C(CH₃)3)3]Sn[((CH₃)2CH)3C₆H₂]2(CH₃)2(C₂H₅) 
• 156420-56-3 C₃H₂OP[C₆H₂(C(CH₃)3)3]Sn[((CH₃)2CH)3C₆H₂]2(CH₃)2 
• 144080-54-6 {(2,4,6-triisopropylphenyl)(OMe)stannyl}(supermesityl)phosphine 
• 144080-55-7 {(2,4,6-triisopropylphenyl)(OH)stannyl}(supermesityl)phosphine 
• 156420-54-1 (((CH₃)2CH)3C₆H₂)2SnOCHCHCH(CH₃)P(((CH₃)3C)3C₆H₂) 
• 156420-55-2 (((CH₃)2CH)3C₆H₂)2SnOC(CH₃)CHCH₂P(((CH₃)3C)3C₆H₂) 
• 156420-53-0 (((CH₃)2CH)3C₆H₂)2SnOCHC(CH₃)CH₂P(((CH₃)3C)3C₆H₂) 
• 156420-52-9 (((CH₃)2CH)3C₆H₂)2SnOCHCHCH₂P(((CH₃)3C)3C₆H₂) 

Relevant academic research and scientific papers

SYNTHESIS AND REACTIVITY OF NEW GERMA- AND STANNAPHOSPHENES

New stable compounds with a germanium (or a tin)-phosphorus double bond have been prepared respectively by a one step reaction between a lithiophosphide and a difluorogermane, or by dehydrofluorination of the corresponding fluorostannyl-phosphine with tert-butyllithium.Various types of cycloadditions (, and ) have been observed with aldehydes, nitrones and α-ethylenic aldehydes and ketones.

A Stable Compound with a Tin-Phosphorus Double Bond: the (2,4,6-Triisopropylphenyl)(supermesityl)stannaphosphene

The stable bis(2,4,6-triisopropylphenyl)(supermesityl)stannaphosphene 1 (supermesityl : 2,4,6-tri-tert-butylphenyl) has been synthesized by dehydrofluorination of the corresponding fluorostannylphosphine by tert-butyllithium; its structure has been evidenced by NMR spectroscopy and by addition of methanol and water onto the tin-phosphorus double bond.