144080-55-7Relevant academic research and scientific papers
SYNTHESIS AND REACTIVITY OF NEW GERMA- AND STANNAPHOSPHENES
Ranaivonjatovo, H.,Escudie, J.,Couret, C.,Rodi, A. Kandri,Satge, J.
, p. 61 - 64 (2007/10/02)
New stable compounds with a germanium (or a tin)-phosphorus double bond have been prepared respectively by a one step reaction between a lithiophosphide and a difluorogermane, or by dehydrofluorination of the corresponding fluorostannyl-phosphine with tert-butyllithium.Various types of cycloadditions (, and ) have been observed with aldehydes, nitrones and α-ethylenic aldehydes and ketones.
A Stable Compound with a Tin-Phosphorus Double Bond: the (2,4,6-Triisopropylphenyl)(supermesityl)stannaphosphene
Ranaivonjatovo, Henri,Escudie, Jean,Couret, Claude,Satge, Jacques
, p. 1047 - 1048 (2007/10/02)
The stable bis(2,4,6-triisopropylphenyl)(supermesityl)stannaphosphene 1 (supermesityl : 2,4,6-tri-tert-butylphenyl) has been synthesized by dehydrofluorination of the corresponding fluorostannylphosphine by tert-butyllithium; its structure has been evidenced by NMR spectroscopy and by addition of methanol and water onto the tin-phosphorus double bond.
