144091-91-8

Upstream product

• 143627-09-2 N,N'-Bis-[1-[(diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine 
• 144091-89-4 tert-butyl diphenylphosphinomethyl ketone dimethylhydrazone 
• 1079-66-9 chloro-diphenylphosphine 
• 69498-77-7 3,3-dimethyl-2-butanone N,N-dimethylhydrazone 
• 100-52-7 benzaldehyde 
• 144116-28-9 Z-tert-Butyl diphenylphosphinomethyl ketone hydrazone 

Downstream Products

• 154790-24-6 cis-{Pt(PPh₂CH=C(Bu(t))-N-N=CHPh)2} 
• 144091-92-9 N-[1-(Diphenyl-phosphinoylmethyl)-2,2-dimethyl-prop-(Z)-ylidene]-N'-[1-phenyl-meth-(E)-ylidene]-hydrazine 

Relevant academic research and scientific papers

Cyclometallation of Azine Phosphines of Type Z,E-PPh2CH2(t-Bu)=N-N=CHR (R = an Aromatic or Heterocyclic Group) involving X-Y (X = C, N or O; Y = H, I or Br) Bond Fission by Platinum(II)

The phosphino hydrazone Z-PPh2CH2C(t-Bu)=NNH2 1 is shown to be a convenient 'reagent' for converting aryl or heterocyclic aldehydes into azines which can rhen be cycloplatinated readily with C-H, C-I, C-Br, N-H or O-H bond fission.Condensation of 1 with b

New Bidentate Ligands PPh2CH2C(tBu)=NNR2 (R=H or Me) and PPh2CH2C(tBu)=NN=CHPh and their Complexes with Group 6 Metal Carbonyls

Treatment of tert-butylmethyl ketone dimethylhydrazone with LiBu, followed by PPh2Cl, gave the crystalline phosphino dimethylhydrazone PPh2CH2C(tBu)=NNMe2, 2a having the C=NNMe2 group in the Z configuration.This phosphine with (nbd=norborna