1440970-58-0

Basic information

• Product Name: ClO₄^(1-)*C₄₇H₃₈N₅PtS₃⁽¹⁺⁾
• CAS NO: 1440970-58-0
• Molecular Weight: 1063.58
• Mol File: 1440970-58-0.mol

Chemical Properties

• CAS DataBase Reference: ClO₄^(1-)*C₄₇H₃₈N₅PtS₃⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: ClO₄^(1-)*C₄₇H₃₈N₅PtS₃⁽¹⁺⁾(1440970-58-0)
• EPA Substance Registry System: ClO₄^(1-)*C₄₇H₃₈N₅PtS₃⁽¹⁺⁾(1440970-58-0)

Safety Data

• Hazardous Substances Data: 1440970-58-0(Hazardous Substances Data)

Upstream product

• 128467-35-6 κ²(N^C²)-(2-phenylpyridine)-κ¹(N)-(2-phenylpyridine)chloro platinum(II) 
• 871868-02-9 N,N-bis[(nitrilo(diphenyl)-λ6-sulfanyl)](diphenyl)-λ6-sulfanediimide 

Relevant articles and documents

Syntheses, crystal structures, and photophysical properties of platinum(II) complexes containing a disulfanenitrile ligand

New PtII complexes of bidendate Ph2S(=N(Ph 2)S≡N)2 (ndsdsd) ligand were prepared, including the homoleptic complex, i.e., [Pt(ndsdsd)2](hfac)2 (1) (hfac: 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato), and the heteroleptic complexes, [Pt(N^N)(ndsdsd)]X2 [N^N = 1,10-phenanthroline (phen) (2), 4,7-diphenylphenanthroline (bathophen) (3); X = PF6 (a) and ClO 4 (b)] and [Pt(C^N)(ndsdsd)]X [C^N = 2-phenylpyridine (ppy) (4) and benzo[h]quinoline (bzq) (5); X = PF6 (a) and ClO4 (b)]. The complexes were characterized by IR, NMR spectroscopy, and elemental analysis. The molecular structures of complexes 1, 2a, and 4b have been elucidated by X-ray crystallographic analysis. The photophysical properties of all complexes were examined. Complexes 2 and 3a are very weakly luminescent in solution, whereas they show highly emissive in the solid state (Φem = 0.110.27).