144101-20-2Relevant academic research and scientific papers
Reagent-Controlled Stereoselective Glycosylation
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Paragraph 0231; 0232; 0233; 0234; 0235; 0236; 0237, (2015/02/19)
Provided are methods for the efficient stereoselective formation of glycosidic bonds, without recourse to prosthetic or directing groups.
Reagent controlled β-specific dehydrative glycosylation reactions with 2-deoxy-sugars
Issa, John Paul,Lloyd, Dina,Steliotes, Emily,Bennett, Clay S.
supporting information, p. 4170 - 4173 (2013/09/12)
N-Sulfonyl imidazoles activate 2-deoxy-sugar hemiacetals for glycosylation presumably by converting them into glycosyl sulfonates in situ. By matching the leaving group ability of the sulfonate with the reactivity of the donor, it is possible to obtain β-
A Stereocontrolled Construction of 2-Deoxy-β-glycosidic Linkages via 1,2-trans-β-Glycosidation of 2-Deoxy-2-glycopyranosyl N,N,N',N'-Tetramethylphosphoroamidates
Hashimoto, Shun-ichi,Yanagiya, Yuki,Honda, Takeshi,Ikegami, Shiro
, p. 1511 - 1514 (2007/10/02)
A stereocontrolled synthesis of 2-deoxy-β-glycosides has been achieved by developing a salient 1,2-trans-glycosidation method with 2-deoxy-2-glycopyranosyl N,N,N',N'-tetramethylphosphoroamidates as glycosyl donors followed by a redu
