144127-22-0

Basic information

• Product Name: 3-Hydroxy-3-methyl-6-phenyl-hexan-2-one
• Synonyms: 3-Hydroxy-3-methyl-6-phenyl-hexan-2-one
• CAS NO: 144127-22-0
• Molecular Weight: 206.285
• Mol File: 144127-22-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Hydroxy-3-methyl-6-phenyl-hexan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Hydroxy-3-methyl-6-phenyl-hexan-2-one(144127-22-0)
• EPA Substance Registry System: 3-Hydroxy-3-methyl-6-phenyl-hexan-2-one(144127-22-0)

Safety Data

• Hazardous Substances Data: 144127-22-0(Hazardous Substances Data)

Upstream product

• 2235-83-8 5-phenyl-2-pentanone 
• 75-05-8 acetonitrile 

Relevant articles and documents

Electroorganic Chemistry. 140. Electroreductively Intra- and Intermolecular Couplings of Ketones with Nitriles

Electroreduction of γ- and δ-cyano ketones in i-PrOH with Sn cathode gave α-hydroxy ketones and their dehydroxylated ketones as the intramolecularly coupled products.Guaiazulene, (-)-valeranone, polyquinanes, dihydrojasmone, methyl dihydrojasmonate, and rosaprostol have been synthesized by utilizing this electroreductive intramolecular coupling of γ- and δ-cyano ketones in one of the key steps.Similarly, electroreduction of a mixture of ketone and nitrile gave the corresponding intermolecularly coupled product.The product obtained by the electroreductive intermolecular coupling of (+)-dihydrocarvone with acetonitrile has been found to be the precursor of an effective chiral ligand for the enantioselective addition of diethylzinc to aldehydes.