1442421-53-5

Basic information

• Product Name: cis-dichloro(pentafluorophenyl)(tri-tert-butylphosphine)gold(III)
• Synonyms: cis-dichloro(pentafluorophenyl)(tri-tert-butylphosphine)gold(III)
• CAS NO: 1442421-53-5
• Molecular Weight: 637.251
• Mol File: 1442421-53-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-dichloro(pentafluorophenyl)(tri-tert-butylphosphine)gold(III)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-dichloro(pentafluorophenyl)(tri-tert-butylphosphine)gold(III)(1442421-53-5)
• EPA Substance Registry System: cis-dichloro(pentafluorophenyl)(tri-tert-butylphosphine)gold(III)(1442421-53-5)

Safety Data

• Hazardous Substances Data: 1442421-53-5(Hazardous Substances Data)

Upstream product

• 1224321-77-0 pentafluorophenyl(tri-tert-butylphosphine)gold(I) 
• 932-72-9 (Dichloroiodo)benzene 
• 69550-28-3 (tri-tert-butylphosphane)gold(I) chloride 
• 363-72-4 Pentafluorobenzene 

Downstream Products

• 69550-28-3 (tri-tert-butylphosphane)gold(I) chloride 
• 434-90-2 decafluorobiphenyl 
• 1244039-16-4 1-methyl-3-(perfluorophenyl)-1H-indole 
• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 

Relevant articles and documents

Cross-coupling of arene-gold(III) complexes

The reactivity of electron-deficient arene-gold(III) complexes toward nucleophilic aromatic and heteroaromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>PtBu3>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied.