1442460-54-9

Basic information

• Product Name: 3-(2-(benzyloxy)phenyl)-2-(1,3-dioxoisoindolin-2-yl)propyl acetate
• CAS NO: 1442460-54-9
• Molecular Weight: 429.472
• Mol File: 1442460-54-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(2-(benzyloxy)phenyl)-2-(1,3-dioxoisoindolin-2-yl)propyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-(benzyloxy)phenyl)-2-(1,3-dioxoisoindolin-2-yl)propyl acetate(1442460-54-9)
• EPA Substance Registry System: 3-(2-(benzyloxy)phenyl)-2-(1,3-dioxoisoindolin-2-yl)propyl acetate(1442460-54-9)

Safety Data

• Hazardous Substances Data: 1442460-54-9(Hazardous Substances Data)

Upstream product

• 51496-94-7 1-allyl-2-(benzyloxy)benzene 
• 136918-14-4 phthalimide 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Relevant articles and documents

Palladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivity

A modified protocol has been identified for Pd-catalyzed intermolecular aminoacetoxylation of terminal and internal alkenes that enables the alkene to be used as the limiting reagent. The results prompt a reassessment of the stereochemical course of these reactions. X-ray crystallographic characterization of two of the products, together with isotopic labeling studies, show that the amidopalladation step switches from a cis-selective process under aerobic conditions to a trans-selective process in the presence of diacetoxyiodobenzene.