144264-98-2

Upstream product

• 144265-04-3 (E)-3'-(4-chlorophenyl)-endo-2-hydroxybicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane 
• 144264-87-9 (E)-exo-2-bromo-3'-phenylbicyclo<2.2.1>heptan-endo-3-spiro-2'-oxirane 
• 144265-11-2 (E)-3-(4-chlorobenzylidene)bicyclo<2.2.1>heptan-2-one 
• 144265-00-9 (E)-3-(4-chlorobenzylidene)bicyclo<2.2.1>heptan-endo-2-ol 
• 144264-86-8 (E)-3-benzylidene-exo-2-bromobicyclo<2.2.1>heptane 
• 144264-84-6 (E)-3-benzylidenebicyclo<2.2.1>heptan-2-one 
• 144264-85-7 (E)-3-benzylidenebicyclo<2.2.1>heptan-endo-2-ol 
• 104-88-1 4-chlorobenzaldehyde 
• 497-38-1 Norbornan-2-on 
• 1067-52-3 tributyltin methoxide 
• 144265-06-5 (E)-3'-(4-chlorophenyl)-endo-2--bicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane 

Downstream Products

• 144265-08-7 (E)-3'-(4-chlorophenyl)-endo-2-methoxybicyclo<2.2.1>heptan-exo-3-spiro-2'-oxirane 

Relevant academic research and scientific papers

Radical Reactions of Bicycloheptan-3-spiro-2'-oxiranes

Tributyltin hydride reduction of 2-bromo- and 2-keto-bicycloheptan-3-spiro-2'-oxiranes gives ring opening of the oxirane-ringes via intermediate 3-(spiro-2'-oxiranyl)bicycloheptan-2-yl radicals, whereas reduction of the analogous 2-(thiocarbonyl)imidazolides) unusually yields the 2-methoxy derivatives and does not proceed by the expected normal fragmentation to yield 3-(spiro-2'-oxiranyl)bicycloheptan-2-yl radicals and subsequent ring-opening of the oxirane rings.