144296-82-2Relevant articles and documents
Alternative syntheses of L-(-)-oleandrose from L-rhamnose. Preparation of glycals
Bredenkamp,Holzapfel,Toerien
, p. 2459 - 2477 (2007/10/02)
L-Rhamnal (2) is prepared from L-rhamnose (3) by use of an improved generalized Fischer-Zach reaction. L-Rhamnal (2) is then converted to L-(-)-oleandrose (1) by stannylene mediated selective methylation and effective hydration. Benzyl α-L-oleandrose (12) is prepared by selective methylation and deoxygenation of L-rhamnose (3).