86972-07-8

Upstream product

• 492-34-2 L-(+)-Oleandrose 
• 100-51-6 benzyl alcohol 
• 86972-06-7 (3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxyhexanal 
• 86972-04-5 (3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxyhexanol 
• 86972-03-4 (3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxy-1-hexene 
• 86972-02-3 (3S,4S,5S)-5-(Benzyloxy)-4-hydroxy-3-methoxy-1-hexene 
• 3359-35-1 (2R,3R,4R,5R,6S)-2-benzyloxy-tetrahydro-6-methyl-2H-pyran-3,4,5-triol 
• 6014-42-2 L-rhamnose 
• 144296-82-2 benzyl 3-O-methyl-α-L-rhamnopyranoside 
• 144296-83-3 benzyl 3-O-methyl-2-O-(thiomethoxythiocarbonyl)-α-L-rhamnopyranoside 

Downstream Products

• 86972-13-6 Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside 
• 86972-09-0 Benzyl 4-O-Acetyl-L-oleandroside (β anomer) 
• 86972-10-3 Benzyl 4-O-Acetyl-L-oleandroside (α anomer) 
• 86972-09-0 Benzyl 4-O-Acetyl-L-oleandroside 

Relevant academic research and scientific papers

Alternative syntheses of L-(-)-oleandrose from L-rhamnose. Preparation of glycals

L-Rhamnal (2) is prepared from L-rhamnose (3) by use of an improved generalized Fischer-Zach reaction. L-Rhamnal (2) is then converted to L-(-)-oleandrose (1) by stannylene mediated selective methylation and effective hydration. Benzyl α-L-oleandrose (12) is prepared by selective methylation and deoxygenation of L-rhamnose (3).