144331-17-9Relevant academic research and scientific papers
On the stereoselectivity of the reaction of N-(9-phenylfluoren-9-yl)aspartate enolates with electrophiles. Synthesis of enantiomerically pure 3-hydroxy-, 3-amino-, and 3-hydroxy-3-methylaspartates
Fernandez-Megia,Paz,Javier Sardina
, p. 7643 - 7652 (2007/10/02)
We have developed efficient and stereoselective preparations of enantiomerically pure (3R)- and (3S)-N-Pf-3-hydroxy- and N-Pf-3-aminoaspartates by reaction of N-Pf-aspartate enolates with electrophilic hydroxylating or aminating reagents. The stereoselect
A stereodivergent chirospecific synthesis of (3R) and (3S) 3-hydroxyaspartates by hydroxylation of aspartate diester enolates
Sardina, F. Javier,Paz, Manuel M.,Fernandez-Megia, Eduardo,De Boer, Richard F.,Alvarez, M. Pilar
, p. 4637 - 4640 (2007/10/02)
A chirospecific and stereodivergent synthesis of N-(9-phenylfluorenyl)-3-hydroxyaspartates by hydroxylation of aspartate enolates is described. The stereochemistry of the newly created chiral center is controlled by the nature of the enolate counterion an
