1443360-55-1Relevant articles and documents
Synthesis, characterization and magnetic properties of an oxido-bridged tetranuclear copper(II) complex
Jana, Mahendra Sekhar,Dey, Sudipto,Priego, José L.,Jiménez-Aparicio, Reyes,Kumar Mondal, Tapan,Roy, Partha
, p. 101 - 106 (2013/07/27)
A copper(II)-Schiff-base complex, [Cu4(O)(L)2(CH 3COO)4] (1) where HL = 4-methyl-2,6-bis(((2-tri- fluoromethyl)phenyl)methyliminomethyl)phenol, has been prepared. It has been characterized by elemental analysis, different spectroscopic methods and single crystal X-ray diffraction study. Single crystal analysis of 1 reveals that four copper atoms coordinate with one oxygen atom forming a distorted tetrahedron in which the oxygen atom occupies the center and copper atoms reside in the corners. The temperature dependent magnetic property of complex 1 shows strong antiferromagnetic interactions between the copper atoms.