144345-22-2Relevant academic research and scientific papers
Photocatalytic Atom-Transfer Radical Addition of Activated Chlorides to Alkenes
Kostromitin, Vladislav S.,Zemtsov, Artem A.,Levin, Vitalij V.,Dilman, Alexander D.
, p. 5336 - 5340 (2021/11/03)
A protocol for performing atom transfer radical addition of activated alkyl chlorides to alkenes is described. The reaction is promoted by blue light in the presence of an organic photocatalyst (3DPA2FBN), serving to generate free radicals, and a copper c
Radical Transfer Catalysis versus Lewis Acid Catalysis by the Copper(I) Chloride-2,2'-Bipyridine Complex: the Effect of the Structure of the Ligand
Udding, Jan H.,Hiemstra, Henk,Speckamp, W. Nico
, p. 1529 - 1530 (2007/10/02)
Cyclization of O-(but-3-enyl)-α-chloroglycolic acid methyl ester 4 catalysed by copper(I) chloride-6,6'-dimethyl-2,2'-bipyridine as catalyst leads to the 6-endo product 6.This is interpreted in terms of a change from a radical to an ionic mechanism.
