1443527-35-2Relevant academic research and scientific papers
Gold meets rhodium: Tandem one-pot synthesis of β-disubstituted ketones via meyer-schuster rearrangement and asymmetric 1,4-addition
Hansmann, Max M.,Hashmi, A. Stephen K.,Lautens, Mark
, p. 3226 - 3229 (2013/07/26)
An asymmetric one-pot tandem Au/Rh-catalyzed synthesis of highly enantioenriched β-disubstituted ketones starting from racemic propargyl alcohols is disclosed. The compatibility of the two metal complexes (Au/Rh) and their orthogonal ligand systems (NHC/d
