144366-00-7Relevant academic research and scientific papers
Unexpected heteroatom-assisted C-4 alkylation of a 1,3-dioxolane
Marot,Philipp,Rollin
, p. 4575 - 4578 (1992)
The reaction of a number of organomagnesium halides with a 4-(2-pyridyl)thiomethyl-1,3-dioxolane 1 mainly afforded C-branched pyridylthiopropanols 2. These versatile synthons resulted from an atypical combined aza-/thia-assisted C-4 alkylation of the cyclic ketal system.
