Tetrahedron Letters p. 4575 - 4578 (1992)
Update date:2022-07-29
Topics:
Marot
Philipp
Rollin
The reaction of a number of organomagnesium halides with a 4-(2-pyridyl)thiomethyl-1,3-dioxolane 1 mainly afforded C-branched pyridylthiopropanols 2. These versatile synthons resulted from an atypical combined aza-/thia-assisted C-4 alkylation of the cyclic ketal system.
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