Unexpected heteroatom-assisted C-4 alkylation of a 1,3-dioxolane

DOI: 10.1016/S0040-4039(00)61316-3

Source and publish data:

Tetrahedron Letters p. 4575 - 4578 (1992)

Update date:2022-07-29

Topics:

Authors:

Marot Marot

Philipp Philipp

Rollin Rollin

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Article abstract of DOI:10.1016/S0040-4039(00)61316-3

The reaction of a number of organomagnesium halides with a 4-(2-pyridyl)thiomethyl-1,3-dioxolane 1 mainly afforded C-branched pyridylthiopropanols 2. These versatile synthons resulted from an atypical combined aza-/thia-assisted C-4 alkylation of the cyclic ketal system.

Full text of DOI:10.1016/S0040-4039(00)61316-3

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