144367-88-4Relevant academic research and scientific papers
The C4-Exo Methylene Isomer of Avermectin B1a: Synthesis via an Allylic Radical and Bioactivity
Fraser-Reid, Bert,Lopez, J. Cristobal,Faghih, Ramin
, p. 6763 - 6768 (1992)
Avermectin B1aΔ4,4a, 2, has been obtained from avermectin B1a, 1, and its bioactivity evaluated.The key step of the transformation is the reduction of an intermediate allylic radical with nBu3SnH.
