1443670-86-7

Basic information

• Product Name: (5R)-2-methyl-5-((E)-1-nitroprop-1-en-2-yl)cyclohexanone
• Synonyms: (5R)-2-methyl-5-((E)-1-nitroprop-1-en-2-yl)cyclohexanone
• CAS NO: 1443670-86-7
• Molecular Weight: 197.234
• Mol File: 1443670-86-7.mol

Chemical Properties

• CAS DataBase Reference: (5R)-2-methyl-5-((E)-1-nitroprop-1-en-2-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (5R)-2-methyl-5-((E)-1-nitroprop-1-en-2-yl)cyclohexanone(1443670-86-7)
• EPA Substance Registry System: (5R)-2-methyl-5-((E)-1-nitroprop-1-en-2-yl)cyclohexanone(1443670-86-7)

Safety Data

• Hazardous Substances Data: 1443670-86-7(Hazardous Substances Data)

Upstream product

• 201012-68-2 (5S)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one 

Relevant articles and documents

Stereoselective nitration of olefins with tBuONO and TEMPO: Direct access to nitroolefins under metal-free conditions

Nitroolefins are essential elements for both synthetic chemistry and medicinal research. Despite significant improvements in nitration of olefin an efficient metal-free synthesis remains elusive so far. Herein, we disclose a new set of reagents to access nitroolefins in a single step under metal-free conditions. A wide range of olefins with diverse functionalities has been nitrated in synthetically useful yields. This transformation is operationally simple and exhibits excellent E-selectivity. Furthermore, site selective nitration in a complex setup makes this method advantageous.