1443677-71-1

Basic information

• Product Name: (2-bromobenzyl)[(1-bromonaphthalen-2-yl)methyl]sulfane
• Synonyms: (2-bromobenzyl)[(1-bromonaphthalen-2-yl)methyl]sulfane
• CAS NO: 1443677-71-1
• Molecular Weight: 422.183
• Mol File: 1443677-71-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-bromobenzyl)[(1-bromonaphthalen-2-yl)methyl]sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-bromobenzyl)[(1-bromonaphthalen-2-yl)methyl]sulfane(1443677-71-1)
• EPA Substance Registry System: (2-bromobenzyl)[(1-bromonaphthalen-2-yl)methyl]sulfane(1443677-71-1)

Safety Data

• Hazardous Substances Data: 1443677-71-1(Hazardous Substances Data)

Upstream product

• 143888-85-1 (2-bromophenyl)methanethiol 
• 37763-43-2 1-bromo-2-(bromomethyl)naphthalene 

Relevant articles and documents

Synthesis and structures of hypervalent organoantimony and organobismuth chlorides containing asymmetric C,E,C-chelating (E = O, S) ligands

Two asymmetric tridentate C,E,C-chelating ligand precursors, 1-Br-2-[(2′-BrC6H4CH2E)CH 2]C10H6 (E = O (1), E = S (2), were prepared in good yield. Lithiation of the two precursors was achieved by a reaction with n-BuLi, and was followed by treatment with SbCl3 or BiCl3 in a 1:1 molar ratio to give four air-stable hypervalent organoantimony and organobismuth chlorides with an asymmetric C,E,C-chelating ligand (E = O, S), i.e. (C6H4CH2OCH2C 10H6)SbCl (3), (C6H4CH 2SCH2C10H6)SbCl (4), (C 6H4CH2OCH2C10H 6)BiCl (5) and (C6H4CH2SCH 2C10H6)BiCl (6). These compounds were characterized by NMR spectroscopy, elemental analysis and melting point determination. X-ray structure analysis of compounds 3-6 revealed that the donor atoms (O, S) are strongly coordinated to the metal atoms (Sb, Bi). Compounds 3-6 exhibit chirality and crystallize as racemic mixtures. The Royal Society of Chemistry 2013.