1444003-10-4Relevant academic research and scientific papers
Photoassisted synthesis of enantiopure alkaloid mimics possessing unprecedented polyheterocyclic cores
Kumar, N.N. Bhuvan,Mukhina, Olga A.,Kutateladze, Andrei G.
, p. 9608 - 9611 (2013/07/26)
Enantiopure alkaloid mimics are synthesized via high yielding intramolecular cycloadditions of photogenerated azaxylylenes tethered to pyrroles, with further growth of molecular complexity via post-photochemical transformations of primary photoproducts. This expeditious access to structurally unprecedented polyheterocyclic cores is being developed in the context of diversity-oriented synthesis, as the modular design allows for rapid "pre-assembly" of diverse photoprecursors from simple building blocks/diversity inputs.
