144403-85-0Relevant academic research and scientific papers
Synthesis of diselenides and selenides from elemental selenium
Krief, Alain,Derock, Michel
, p. 3083 - 3086 (2007/10/03)
Sodium hydride is able to reduce elemental selenium to sodium diselenide (Na2Se2), but not to sodium selenide (Na2Se). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).
On the Racemization of α-Hetero-Substituted Benzyllithium Compounds
Ahlbrecht, Hubertus,Harbach, Juergen,Hoffmann, Reinhard W.,Ruhland, Thomas
, p. 211 - 216 (2007/10/02)
Benzyllithium compounds carrying a benzylthio substituent (6), a benzylseleno substituent (8), and an isopropyl(methyl)amino substituent 14 have been generated.Racemization barriers have been determined in THF by monitoring the coalescence of signals of d
