144424-52-2Relevant academic research and scientific papers
Synthesis and Structure of a Novel Cyclic Polysulfide, 2,4,6-Trisphenyloctathionane
Takeda, Nobuhiro,Tokitoh, Norihiro,Imakubo, Tatsuro,Goto, Midori,Okazaki, Renji
, p. 2757 - 2764 (2007/10/03)
A novel cyclic polysulfide, octathionane TbtCHS8 (7; Tbt=2,4,6-trisphenyl) was synthesized by thermal reaction of the corresponding diazomethane TbtCHN2 with cyclooctasulfur (S8) in benzene in the dark.Molecular structure of 7 was determined by X-ray crystallographic analysis and the geometry of the C8 ring was compared with that of theoretically optimized cyclononanosulfur (S9).Desulfuration of 7 by triphenylphosphine afforded the corresponding pentathiane TbtCHS5.
1,2,3,4,5,6,7,8-Octathionane, a Novel Cyclic Polysulfide. Synthesis and Crystal Structure
Tokitoh, Norihiro,Takeda, Nobuhiro,Imakubo, Tatsuro,Goto, Midori,Okazaki, Renji
, p. 1599 - 1602 (2007/10/02)
Thermal reaction of a sterically bulky diazomethane with elemental sulfur in benzene afforded a novel cyclic polysulfide, 1,2,3,4,5,6,7,8-octathionane (1).Molecular structure of 1 was determined by X-ray crystallographic analysis and the geometry of its C
