171620-66-9

Upstream product

• 115160-05-9 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 
• 171620-65-8 2,4,6-trisbenzaldehyde 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 144442-79-5 N,N'-Bis-[1-[2,4,6-tris-(bis-trimethylsilanyl-methyl)-phenyl]-meth-(E)-ylidene]-hydrazine 
• 144424-53-3 (2S,3S)-2,3-Bis-[2,4,6-tris-(bis-trimethylsilanyl-methyl)-phenyl]-thiirane 
• 144424-51-1 2,4,6-trisphenyloctathionane 
• 144424-54-4 2,4-Bis-(bis-trimethylsilanyl-methyl)-7,7-bis-trimethylsilanyl-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-triene 
• 144424-52-2 1,3,5-Tris-(bis-trimethylsilanyl-methyl)-2-diazomethyl-benzene 
• 157981-89-0 2,4,6-trisphenylpentathiane 

Relevant academic research and scientific papers

Synthesis and Structure of a Novel Cyclic Polysulfide, 2,4,6-Trisphenyloctathionane

A novel cyclic polysulfide, octathionane TbtCHS8 (7; Tbt=2,4,6-trisphenyl) was synthesized by thermal reaction of the corresponding diazomethane TbtCHN2 with cyclooctasulfur (S8) in benzene in the dark.Molecular structure of 7 was determined by X-ray crystallographic analysis and the geometry of the C8 ring was compared with that of theoretically optimized cyclononanosulfur (S9).Desulfuration of 7 by triphenylphosphine afforded the corresponding pentathiane TbtCHS5.

1,2,3,4,5,6,7,8-Octathionane, a Novel Cyclic Polysulfide. Synthesis and Crystal Structure

Thermal reaction of a sterically bulky diazomethane with elemental sulfur in benzene afforded a novel cyclic polysulfide, 1,2,3,4,5,6,7,8-octathionane (1).Molecular structure of 1 was determined by X-ray crystallographic analysis and the geometry of its C