144436-50-0

Basic information

• Product Name: [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2]
• Synonyms: [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2]
• CAS NO: 144436-50-0
• Molecular Weight: 900.755
• Mol File: 144436-50-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2](CAS DataBase Reference)
• NIST Chemistry Reference: [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2](144436-50-0)
• EPA Substance Registry System: [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2](144436-50-0)

Safety Data

• Hazardous Substances Data: 144436-50-0(Hazardous Substances Data)

Upstream product

• 13826-27-2 2,2'-bis(1,3,2-benzodioxaborole) 
• 14653-50-0 [rhodium(I)chloride(triphenylphosphine)2]1 
• 186790-63-6 bis(4-methylcatecholato)diborane⁽⁴⁾ 
• 14694-95-2 Wilkinson's catalyst 
• 58512-07-5 RhHCl(BO₂C₆H₄)(P(C₆H₅)3)2 
• 58512-07-5 [(Ph₃P)2RhCl(H)(phenylene-1,2-dioxyboryl)] 
• 274-07-7 benzo[1,3,2]dioxaborole 

Relevant articles and documents

Reaction between rhodium(III) bisboryls and diborane(4) compounds: Evidence for a σ-bond metathesis process

The rhodium bis(boryl) complex [RhCl(PPh3)2{B(cat)}2] (cat = 1,2-O2C6H4) reacts with the diborane(4) compounds B2(O2R)2 {O2R = 1,2-O2C6H3Me-4, 1,2-O2C6H2But2-3,5 and dimethyl-L-tartrate [OCH(CO2Me)CH(CO2Me)O]} affording unsymmetrical metal bis(boryls) [RhCl(PPh3)2{B(cat)}-{B(O2R)}] and diborane(4) compounds (cat)B-B(O2R), one possible mechanism for which involves σ-bond metathesis.