1444444-36-3

Basic information

• Product Name: 2,3-dihydro-2-methyl-2-[(4-methylphenyl)sulfonyl]-1H-inden-1-imine
• Synonyms: 2,3-dihydro-2-methyl-2-[(4-methylphenyl)sulfonyl]-1H-inden-1-imine
• CAS NO: 1444444-36-3
• Molecular Weight: 299.393
• Mol File: 1444444-36-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-dihydro-2-methyl-2-[(4-methylphenyl)sulfonyl]-1H-inden-1-imine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-dihydro-2-methyl-2-[(4-methylphenyl)sulfonyl]-1H-inden-1-imine(1444444-36-3)
• EPA Substance Registry System: 2,3-dihydro-2-methyl-2-[(4-methylphenyl)sulfonyl]-1H-inden-1-imine(1444444-36-3)

Safety Data

• Hazardous Substances Data: 1444444-36-3(Hazardous Substances Data)

Upstream product

• 58379-80-9 1-(toluene-4-sulfonyl)-ethyl isocyanide 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Relevant articles and documents

Remote aryl cyanation via isocyanide-cyanide rearrangement on tosylmethyl isocyanide derivatives

The reaction of alkyl tosylmethyl isocyanides and 2-bromobenzyl bromides in the presence of t-BuLi gives rise to a cascade reaction to give unexpected 2-substituted 2,3-dihydro-1H-indenimines which, upon treatment with t-BuOK, rearrange to 2-vinylbenzonitriles in high overall yields. This simple procedure represents a new approach to the synthesis of aromatic nitriles via isocyanide-cyanide interconversion.