144485-53-0

Upstream product

• 1206803-29-3 p-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-triethyl-silyl-α-D-mannopyranoside 
• 1397285-38-9 p-methoxyphenyl 6-O-triisopropylsilyl-α-D-mannoside 
• 1397285-39-0 p-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-triisopropylsilyl-α-D-mannoside 
• 28541-75-5 p-methoxyphenyl α-D-mannopyranoside 
• 344914-56-3 p-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-(4,4'-dimethoxytrityl)-α-D-mannopyranoside 
• 344914-55-2 p-methoxyphenyl 6-O-(4,4'-dimethoxytrityl)-α-D-mannopyranoside 

Downstream Products

• 344914-57-4 p-methoxyphenyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 173597-20-1 p-methoxyphenyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 344914-59-6 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α,β-D-mannopyranosyl fluoride 
• 344914-63-2 methyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 344914-58-5 p-methoxyphenyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 1397285-40-3 (Z)-p-methoxyphenyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannohex-5-enopyranoside 
• 1397285-41-4 (E)-p-methoxyphenyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannohex-5-enopyranoside 
• 949886-74-2 para-methoxyphenyl 2,3,4-tri-O-benzyl-7,7-dibromo-6,7-dideoxy-α-D-manno-hept-6-enopyranoside 
• 949886-82-2 2,3,4-tri-O-benzyl-5a-difluoro-5a-carba-β-D-mannopyranose 
• 949886-80-0 2,3,4-tri-O-benzyl-5a-difluoro-5a-carba-α-D-mannopyranose 
• 949886-79-7 2,3,4-tri-O-benzyl-6,6,7,7-tetradehydro-6,7,8-trideoxy-5a-difluoro-5a-carba-β-D-manno-octopyranose 
• 949886-78-6 2,3,4-tri-O-benzyl-6,6,7,7-tetradehydro-6,7,8-trideoxy-5a-difluoro-5a-carba-α-D-manno-octopyranose 
• 949886-77-5 2,6-anhydro-3,4,5-tri-O-benzyl-7,7,8,8-tetradehydro-1,7,8,9-tetradeoxy-1,1-difluoro-D-manno-non-1-enitol 
• 949886-76-4 2,3,4-tri-O-benzyl-6,6,7,7-tetradehydro-6,7,8-trideoxy-D-manno-octono-1,5-lactone 

Relevant academic research and scientific papers

Glycosylations of cyclopropyl-modified carbohydrates: Remarkable β-selectivity using a mannose building block

A mannosyl donor bearing a spiroannulated cyclopropane unit at C-5 has been prepared, and its behavior in glycosylation reactions investigated. Selectivities in favor of the β-anomer were observed. Corresponding di- and trisaccharides incorporating the ri

Glycosylations of cyclopropyl-modified carbohydrates: Remarkable β-selectivity using a mannose building block

A mannosyl donor bearing a spiroannulated cyclopropane unit at C-5 has been prepared, and its behavior in glycosylation reactions investigated. Selectivities in favor of the β-anomer were observed. Corresponding di- and trisaccharides incorporating the ri

Highly efficient and mild method for regioselective de-O-benzylation of saccharides by Co2(CO)8-Et3SiH-CO reagent system

[Chemical equation presented] A highly efficient and mild method for the de-O-benzylation of protected saccharides was developed by transforming terminal benzyl ethers Into silyl ethers using Co2(CO)8-Et 3SIH under 1 atm of CO. The method was successfully used for the de-O-benzylatlon of perbenzylated monosaccharides with various anomerlc protecting groups, as well as natural disaccharldes and trisaccharides such as sucrose, raffinose, and melezltose In good yields (>80%).

gem-Difluoro-carbasugars, the cases of mannopyranose and galactopyranose

5a-Difluoro-5a-carbamannopyranose (gem-difluoro-carbamannopyranose) and 5a-difluoro-5a-carbagalactopyranose (gem-difluoro-carbagalactopyranose), close congeners of their respective natural sugars, in which the endocyclic oxygen atom has been replaced by a

Synthesis of inositol glycan cyclic phosphates

An efficient synthesis of tri-, tetra-, and pentasaccharide cyclic phosphates 1-5, structurally related to natural inositol phosphate glycans, is reported. The title compounds were assembled by PhSeOTf-promoted glycosylation of the known glucosamine precu