144500-96-9

Basic information

• Product Name: Phosphine, 1,3-butadiene-1,4-diylidenebis[[2,4,6-tris(1,1-dimethylethyl)phenyl]-
• CAS NO: 144500-96-9
• Molecular Formula: C40H60P2
• Molecular Weight: 602.864
• Mol File: 144500-96-9.mol

Chemical Properties

• CAS DataBase Reference: Phosphine, 1,3-butadiene-1,4-diylidenebis[[2,4,6-tris(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, 1,3-butadiene-1,4-diylidenebis[[2,4,6-tris(1,1-dimethylethyl)phenyl]-(144500-96-9)
• EPA Substance Registry System: Phosphine, 1,3-butadiene-1,4-diylidenebis[[2,4,6-tris(1,1-dimethylethyl)phenyl]-(144500-96-9)

Safety Data

• Hazardous Substances Data: 144500-96-9(Hazardous Substances Data)

Upstream product

• 313703-76-3 Bis[ethynyl(2,4,6-tert-butylphenyl)phosphanyl]butadiyne 
• 132363-63-4 1,6-Bis(trimethylsilyl)-3,4-bis(2,4,6-tri-tert-butylphenyl)-3,4-diphospha-1,5-hexadiyne 
• 128270-51-9 3,4-bis(trimethylsilyl)-1,6-bis(2,4,6-tri-t-butylphenyl)-1,6-diphospha-1,2,4,5-hexatetraene 

Downstream Products

• 144500-94-7 (E,E)-3,4-bis(2,4,6-tri-t-butylphenylphosphinidene)cyclobutene 

Relevant articles and documents

Preparation and Isomerization of 3,4-Bis(2,4,6-tri-t-butylphenylphosphinidene)cyclobutenes

(E,E)- and (E,Z)-3,4-Bis(2,4,6-tri-t-butylphenylphosphinidene)cyclobutenes were prepared by desilylation reaction of the corresponding 1,2-bis(trimethylsilyl)cyclobutenes or by thermal isomerization reaction of 1,6-bis(2,4,6-tri-t-butylphenyl)-1,6-diphosp

1λ3?2,6λ3?2-Diphospha-1,2,4,5-hexatetraen aus 1,6-Di-H-1,6-diphosphino-2,4-hexadiin

1,6-Di-H-1,6-diphosphino-2,4-hexadiyne 5 undergoes a base-catalyzed heteropropargylic rearrangement to give 1,6-diphosphahexatetraene 3a, which forms stereoselective 3,4-diphosphamethylencyclobutene 4a by valence isomerisation.