1λ3?2,6λ3?2-Diphospha-1,2,4,5-hexatetraen aus 1,6-Di-H-1,6-diphosphino-2,4-hexadiin

DOI: 10.1016/0040-4039(95)01292-P

Source and publish data:

Tetrahedron Letters p. 6429 - 6432 (1995)

Update date:2022-08-29

Topics:

Authors:

Maerkl, Gottfried

Hennig, Ruediger

Noeth, Heinrich

Schmidt, Martin

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Article abstract of DOI:10.1016/0040-4039(95)01292-P

1,6-Di-H-1,6-diphosphino-2,4-hexadiyne 5 undergoes a base-catalyzed heteropropargylic rearrangement to give 1,6-diphosphahexatetraene 3a, which forms stereoselective 3,4-diphosphamethylencyclobutene 4a by valence isomerisation.

Full text of DOI:10.1016/0040-4039(95)01292-P

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