1445609-07-3Relevant academic research and scientific papers
Synthesis of 2,7-diazabicyclo[22.1]heptenes by N-O bond cleavage of arylnitroso diels-alder 1,2-dihydropyridine cycloadducts
Berti, Francesco,Di Bussolo, Valeria,Pineschi, Mauro
, p. 647 - 652 (2015)
The cleavage of the N-O bond of nitrosoarene-derived cycloadducts with 1,2-dihydropyridines gives different products depending on the protecting group of the starting dihydropyridine and reaction conditions. The use of catalytic amounts of CuCl in non-nuc
Synthesis of protected (1-phenyl-1 H -pyrrol-2-yl)-alkane-1-amines from phenylnitroso diels-alder adducts with 1,2-dihydropyridines
Berti, Francesco,Di Bussolo, Valeria,Pineschi, Mauro
, p. 7324 - 7329 (2013/08/15)
The reductive cleavage of nitrosobenzene-derived cycloadducts with appropriately protected 1,2-dihydropyridines allows a novel and simple obtainment of substituted N-[1-(1-phenyl-1H-pyrrol-2-yl)alkylamides. This synthesis can also be carried out in a very simple, mild, and practical one-pot procedure without isolation of the corresponding nitrosobenzene cycloadduct by means of catalytic amounts of CuCl.
