144562-57-2Relevant academic research and scientific papers
Cis-3,5-cyclohexadiene-1,2-diol derivatives: Facial selectivity in their Diels-Alder reactions with ethylenic, acetylenic and azo dienophiles
Ogbomo, Sunny M.,Burnell, D. Jean
, p. 3838 - 3848 (2008/09/18)
The Diels-Alder reactions of maleimide with the acetonide derivative (6a) of cis-3,5-cyclohexadiene-1,2-diol (1a) in various solvents showed facial selectivities ranging from 1: 1 to 1: 9. The same derivative 6a reacted in benzene with ethylenic dienophil
?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide
Gillard, James R.,Burnell, D. Jean
, p. 1296 - 1307 (2007/10/02)
N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The
