80409-74-1

Upstream product

• 1165952-92-0 cyclohexa-1,4-diene 
• 64287-98-5 [1R(S),2S(R),4S(R),5S(R)]-4,5-dibromocyclohexane-1,2-diol 
• 42846-36-6 trans-4,5-dibromo-1-cyclohexene 
• 92241-42-4 (2R,3aR,6R,7aS)-5,6-Dibromo-2-phenyl-hexahydro-benzo[1,3]dioxole 
• 80409-80-9 (2α,3aβ,5β,6α,7aβ)-5,6-dibromohexahydro-2-phenyl-1,3-benzodioxole 

Downstream Products

• 124068-32-2 C₂₃H₂₀O₂ 
• 80409-79-6 C₂₇H₂₂O₂ 
• 80409-76-3 C₂₇H₂₂O₂ 
• 92343-32-3 C₂₇H₂₂O₂ 
• 144562-57-2 (2α,3aα,5aβ,6α,6aβ,8β,9aβ,10α,10aβ,10bα)-3a,5a,6,6a,9a,10,10a,10b-octahydro-2,8-diphenyl-6,10-ethenonaphtho<1,2-d:6,7-d'>bis<1,3>dioxole 
• 913836-50-7 diethyl (2α,3aα,4β,7β,7aα)-3a,4,7,7a-tetrahydro-2-phenyl-4,7-etheno-1,3-dioxolo[4,5-d]pyridazine-5,6-dicarboxylate 
• 913836-49-4 (2α,3aα,4β,10β,10aα)-3a,4,10,10a-tetrahydro-2,7-diphenyl-4,10-etheno-6H-1,3-dioxolo[4,5-d][1,2,4]triazolo[1,2-a]pyridazine-6,8(7H)-dione 
• 144607-54-5 (2α,3aα,4β,4aα,7aα,8β,8aα)-4a,7a,8,8a-tetrahydro-2,6-diphenyl-4,8-etheno-4H-1,3-dioxolo<4,5-f>isoindole-5,7(3aH,6H)-dione 
• 144607-53-4 (2α,3aα,4α,4aβ,7aβ,8α,8aα)-4a,7a,8,8a-tetrahydro-2,6-diphenyl-4,8-etheno-4H-1,3-dioxolo<4,5-f>isoindole-5,7(3aH,6H)-dione 

Relevant academic research and scientific papers

?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide

N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The

Chemistry of Benzene-Anthracene Cyclodimers

Synthesis of the formal s + 4?s> and s + 2?s> adducts of benzene and anthracene (1 and 2) has made possible the observation of features on the potential-energy surfaces that govern Woodward-Hoffmann-allowed and -forbidden cycloreversions.The thermal dissociation of 1 is not chemiluminescent in spite of favorable kinetic and thermodynamic parameters, and its photochemical dissociation yields excited anthracene in very high efficiency (ΦAn* = 0.80).The enthropy of activation in the thermal dissociation of 2 is negative, and the photochemical dissociation of 2 yields excited anthracene in low but appreciable efficiency (ΦAn* = 0.08).Comparision of these data clearly demonstrates orbital symmetry control of both the ground- and excited-state reactions.