144582-47-8

Basic information

• Product Name: methyl 2'-acetoxy-4'-methoxycinnamate
• CAS NO: 144582-47-8
• Molecular Weight: 250.251
• Mol File: 144582-47-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2'-acetoxy-4'-methoxycinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2'-acetoxy-4'-methoxycinnamate(144582-47-8)
• EPA Substance Registry System: methyl 2'-acetoxy-4'-methoxycinnamate(144582-47-8)

Safety Data

• Hazardous Substances Data: 144582-47-8(Hazardous Substances Data)

Upstream product

• 531-59-9 7-methoxycoumarin 
• 93198-68-6 (E)-methyl 2’-hydroxy-4’-methoxycinnamate 
• 108-24-7 acetic anhydride 

Downstream Products

• 93198-68-6 (E)-methyl 2’-hydroxy-4’-methoxycinnamate 
• 117285-67-3 methyl 3-(2-acetoxy-4-methoxyphenyl)propanoate 
• 450-16-8 geijerin 
• 69471-28-9 methyl 3-(2'-hydroxy-4'-methoxyphenyl)propanoate 
• 117285-77-5 methyl 3-(5-acetyl-2-hydroxy-4-methoxyphenyl)propanoate 
• 144582-48-9 (E)-3-(4-Methoxy-2-propionyloxy-phenyl)-acrylic acid methyl ester 
• 117285-82-2 methyl 3-(2-hydroxy-4-methoxy-5-propanoylphenyl)propanoate 
• 144582-49-0 (E)-3-(2-Isobutyryloxy-4-methoxy-phenyl)-acrylic acid methyl ester 
• 117285-71-9 methyl 3-(4-methoxy-2-propanoyloxyphenyl)propanoate 
• 117285-75-3 methyl 3-(2-hydroxy-5-isovaleryl-4-methoxyphenyl)propanoate 
• 117285-78-6 3-Methyl-butyric acid 5-methoxy-2-((E)-2-methoxycarbonyl-vinyl)-phenyl ester 
• 117285-72-0 methyl 3-(2-isobutanoyloxy-4-methoxyphenyl)propanoate 
• 144582-53-6 (E)-3-[2-(2,2-Dimethyl-propionyloxy)-4-methoxy-phenyl]-acrylic acid methyl ester 
• 117285-86-6 6-benzoyl-7-methoxycoumarin 

Relevant articles and documents

EFFICIENT, HIGHLY REGIOSELECTIVE FRIES REARRANGEMENTS OF METHYL 3-(2-ACYLOXY-4-METHOXYPHENYL)PROPANOATES: THE FIRST TOTAL SYNTHESIS OF THE LINEAR ACYLATED COUMARINS GEIJERIN AND DEHYDROGEIJERIN.

Aluminium chloride catalysed para-Fries rearrangement of methyl 3-(2-acyloxy-4-methoxyphenyl)propanoates (5) in nitromethane furnishes the corresponding 5-acylated products (6) cleanly and in high yield.The rearrangement products may be converted into 6-a