1445971-88-9

Basic information

• Product Name: (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) chloride
• Synonyms: (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) chloride
• CAS NO: 1445971-88-9
• Molecular Weight: 643.441
• Mol File: 1445971-88-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) chloride(1445971-88-9)
• EPA Substance Registry System: (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) chloride(1445971-88-9)

Safety Data

• Hazardous Substances Data: 1445971-88-9(Hazardous Substances Data)

Upstream product

• 21264-30-2 dichloro bis(acetonitrile) palladium(II) 
• 1445947-50-1 1,5-bis((diphenylphosphinoyl)methyl)-2,4-dimethylbenzene 
• 4559-70-0 Diphenylphosphine oxide 
• 1585-15-5 4,6-bis(chloromethyl)-m-xylene 

Downstream Products

• 1445971-89-0 (2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) iodide 
• 1445971-87-8 acetoxy(2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II) 
• 1445971-92-5 1-(aquapalladium(II))-2,6-bis((diphenylphosphino)methyl)-3,5-dimethylbenzene trifluoromethylsulfonate 

Relevant articles and documents

Chemoselective transfer hydrogenation of α,β-unsaturated ketones catalyzed by pincer-Pd complexes using alcohol as a hydrogen source

A pincer-Pd complex was utilized in the chemoselective transfer hydrogenation of α,β-unsaturated ketones using n-BuOH as a hydrogen source and solvent. Good to excellent yields were obtained for various substrates even with reducible groups. Based on deuterium-labeling experiments, the reaction mechanism is proposed to occur via a pincer-Pd-hydride intermediate.