1446012-86-7Relevant academic research and scientific papers
First asymmetric synthesis of planar chiral [2.2]metacyclophanes
Blangetti, Marco,Mueller-Bunz, Helge,O'Shea, Donal F.
, p. 6125 - 6127 (2013)
A general three step asymmetric synthesis of planar chiral [2.2]metacyclophanes utilizing selective benzylic and aryl metalations is described. The final enantioselective step is achieved using a (-)-sparteine mediated aryl metalation, following which ele
