52010-39-6Relevant academic research and scientific papers
Ruthenium-catalyzed ortho-C-H halogenations of benzamides
Wang, Lianhui,Ackermann, Lutz
supporting information, p. 1083 - 1085 (2014/01/17)
[Ru3(CO)12] and AgO2C(1-Ad) enabled the first ruthenium-catalyzed intermolecular halogenations of arenes via C-H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were ach
First asymmetric synthesis of planar chiral [2.2]metacyclophanes
Blangetti, Marco,Mueller-Bunz, Helge,O'Shea, Donal F.
supporting information, p. 6125 - 6127 (2013/07/26)
A general three step asymmetric synthesis of planar chiral [2.2]metacyclophanes utilizing selective benzylic and aryl metalations is described. The final enantioselective step is achieved using a (-)-sparteine mediated aryl metalation, following which ele
