1446102-05-1Relevant articles and documents
Aryl nitrene rearrangements: Spectroscopic observation of a benzazirine and its ring expansion to a ketenimine by heavy-atom tunneling
Inui, Hiroshi,Sawada, Kazuhiro,Oishi, Shigero,Ushida, Kiminori,McMahon, Robert J.
, p. 10246 - 10249 (2013)
In the photodecompositions of 4-methoxyphenyl azide (1) and 4-methylthiophenyl azide (5) in argon matrixes at cryogenic temperatures, benzazirine intermediates were identified on the basis of IR spectra. As expected, the benzazirines photochemically rearr