2101-87-3

Basic information

• Product Name: 4-METHOXYPHENYLAZIDE
• Synonyms: 4-METHOXYPHENYLAZIDE;1-Azido-4-methoxybenzene;4-Azidoanisole;4-Methoxy-1-azidobenzene;Methyl 4-azidophenyl ether;p-Anisyl azide;4-Azidoanisole solution;4-Azidoanisole solution ~0.5 M in tert-butyl methyl ether, >=90.0% (HPLC)
• CAS NO: 2101-87-3
• Molecular Formula: C₇H₇N₃O
• Molecular Weight: 149.15
• Mol File: 2101-87-3.mol
• Article Data: 182

Chemical Properties

• Melting Point: 36 °C
• Boiling Point: °Cat760mmHg
• Flash Point: -30℃
• Appearance: /
• Density: g/cm³
• Storage Temp.: ?20°C
• Solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
• BRN: 3609304
• CAS DataBase Reference: 4-METHOXYPHENYLAZIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXYPHENYLAZIDE(2101-87-3)
• EPA Substance Registry System: 4-METHOXYPHENYLAZIDE(2101-87-3)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-38-43
• Safety Statements: 16-36/37
• RIDADR: UN 2398 3 / PGII
• WGK Germany: 3
• Hazardous Substances Data: 2101-87-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7N3O/c1-11-7-4-2-6(3-5-7)9-10-8/h2-5H,1H3

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 150-76-5 4-methoxy-phenol 
• 100-66-3 methoxybenzene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 32785-42-5 para-methoxyphenyl pentazole 
• 104-94-9 4-methoxy-aniline 
• 623-12-1 4-chloromethoxybenzene 
• 1258238-85-5 2-(4-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione 
• 1516-21-8 4-methoxynitrosobenzene 
• 49638-61-1 1-(4-methoxy-phenylazo)-aziridine 
• 4648-54-8 trimethylsilylazide 
• 104-93-8 p-methylanizole 
• 696-62-8 para-iodoanisole 
• 540-37-4 p-aminoiodobenzene 

Downstream Products

• 104-94-9 4-methoxy-aniline 
• 90861-94-2 4-methoxy-2-tetrahydro-2-thienylaniline 
• 110-00-9 furan 
• 4282-33-1 dimethyl 3,4-furandicarboxylate 
• 68535-49-9 1-(4-methoxyphenyl)-1H-[1,2,3]triazole 
• 4953-05-3 dimethyl 1-(4-methoxyphenyl)-1H-1,2,3-triazole-4,5-dicarboxylate 
• 122942-58-9 (Z)-3-((4-methoxyphenyl)amino)-1,3-diphenylprop-2-en-1-one 
• 122942-56-7 [3-(4-Methoxy-phenyl)-5-phenyl-3H-[1,2,3]triazol-4-yl]-phenyl-methanone 
• 122942-48-7 [1-(4-Methoxy-phenyl)-5-phenyl-1H-[1,2,3]triazol-4-yl]-phenyl-methanone 
• 163071-43-0 3-(4-Methoxy-phenyl)-5-pyridin-2-yl-3H-[1,2,3]triazol-4-ylamine 
• 58014-26-9 [4-(4-Methoxy-phenyl-NNO-azoxy)-phenyl]-dimethyl-amine 
• 110684-16-7 2-[3-(4-Methoxy-phenyl)-4,5-dihydro-3H-[1,2,3]triazol-4-yl]-pyridine 
• 55643-90-8 4-[3-(4-methoxy-phenyl)-4,5-dihydro-3H-[1,2,3]triazol-4-yl]-pyridine 
• 203261-69-2 1-(4-methoxyphenyl)-2-(4-pyridyl)aziridine 

Relevant articles and documents

Transient resonance Raman and density functional theory investigation of 4-methoxyphenylnitrenium and 4-ethoxyphenylnitrenium ions

This paper presents a transient resonance Raman and density functional theory study of 4-methoxyphenylnitrenium and 4-ethoxyphenylnitrenium ions in a largely aqueous environment. The transient Raman bands observed in conjunction with the (U)BPW91/cc-PVDZ

Photochemistry of Aryl Pentazoles: Para -Methoxyphenylpentazole

The photolysis of para-methoxyphenyl pentazole (MeOPP) in methylcyanide (MeCN), investigated in the far UV (FUV) and near UV (NUV) is compared with the photolysis of para-methoxyphenyl azide (MeOPA). The main photoproduct of MeOPP is MeOPA, which, due to

Helicenoid-based bis-1,2,3-triazole tweezer: Synthesis and selective iodide sensing

Novel helicenoid based 1,2,3-triazole tweezer 4 was synthesized using a multistep synthetic protocol with high yields from 2,7-Dihydroxynaphtlene 3 as a precursor. This helicenoid-based bis-1,2,3-triazole tweezer 4 selectively causes non-covalent interact

Combinatorial synthesis of new fluorescent scaffolds using click chemistry

Azides and acetylenes are bio-orthogonal functional groups that can be readily coupled using copper(I)- or ruthenium(II)- catalyzed 1,3-dipolar cycloaddition reactions. Using non-fluorescent aromatic azides and aromatic acetylenes, covering a range of electron rich and poor building blocks, the Huisgen cycloaddition afford 1,4-disubstituted or 1,5-disubstituted 1,2,3-triazoles. Using a combinatorial approach by running reaction in parallel in polypropylene 96-well plates we discovered several new fluorescent 1,2,3-triazoles scaffolds. These compounds show diverse interactions with biomolecules that could find applications in biology in, for example, fluorescence microscopy or biomolecule quantification.

Discovery of new tranylcypromine derivatives as highly potent LSD1 inhibitors

Tranylcypromine (TCP)-based structural modifications lead to the discovery of new LSD1 inhibitors, of which compounds 26b and 29b effectively inhibit LSD1 with the IC50 values of 17 and 11 nM, respectively and also show good selectivity over MAO-B. Mechanistic studies showed that compound 29b concentration-dependently induced H3K4me1/2 accumulation in LSD1 overexpressed MGC-803 cells and also inhibited metastasis of MGC-803 cells. Collectively, both compounds could be promising lead compounds for further investigation.