1446239-69-5Relevant academic research and scientific papers
Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes
Long, Peng-Wei,Bai, Xing-Feng,Ye, Fei,Li, Li,Xu, Zheng,Yang, Ke-Fang,Cui, Yu-Ming,Zheng, Zhan-Jiang,Xu, Li-Wen
supporting information, p. 2825 - 2830 (2018/08/17)
Catalytic silicon-carbon or silicon-heteroatom bond-forming hydrosilylation has become increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein we report a platinum-catalyzed one-pot and tandem hydrosilylation/cyclization of OH-containing alkynes with dihydrosilanes, allowing for facile synthesis of six-membered organosilicon compounds, including silyloxycycles and cyclic siloxanes in high yields and with good stereoselectivities. (Figure presented.).
Enantioselective relay catalytic cascade intramolecular hydrosiloxylation and mukaiyama aldol reaction
Wang, Pu-Sheng,Li, Kang-Nan,Zhou, Xiao-Le,Wu, Xiang,Han, Zhi-Yong,Guo, Rui,Gong, Liu-Zhu
supporting information, p. 6234 - 6238 (2013/07/05)
Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme). Copyright
