1446280-09-6

Basic information

• Product Name: C₁₂H₁₁⁽²⁾H₄NO
• Synonyms: C₁₂H₁₁⁽²⁾H₄NO
• CAS NO: 1446280-09-6
• Molecular Weight: 193.225
• Mol File: 1446280-09-6.mol

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₁⁽²⁾H₄NO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₁⁽²⁾H₄NO(1446280-09-6)
• EPA Substance Registry System: C₁₂H₁₁⁽²⁾H₄NO(1446280-09-6)

Safety Data

• Hazardous Substances Data: 1446280-09-6(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 1370704-99-6 N,N-dimethylbenzamide-d5 
• 611-74-5 N,N-dimethylbenzamide 

Relevant articles and documents

Ruthenium(II)-Catalyzed Oxidant-Free C–H Olefination of Aromatic Carboxamides with Allyl Acetate

An inexpensive ruthenium-catalyzed direct C–H olefination of aromatic carboxamides with allyl acetate was developed. This external oxidant-free protocol provided an efficient route for the synthesis of useful trans-styrene derivatives in high to excellent yields. The olefination reaction exhibited excellent regioselectivities and allowed the presence of a wide range of functional groups, such as OMe, F, Cl, Br, I, CF3, NMe2, as well as NO2. (Figure presented.).

Oxidant-free Rh(III)-catalyzed direct C-H olefination of arenes with allyl acetates

Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing group. The catalyst undergoes a redox neutral process, and high to excellent yields of trans-products are obtained. This protocol exhibits a wide spectrum of functionality compatibility because of the simple reaction conditions employed and provides a highly effective synthetic method in the realm of C-H olefination.