144632-53-1

Basic information

• Product Name: Benzeneacetaldehyde, a-methyl-a-(2-oxopropyl)-
• CAS NO: 144632-53-1
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 144632-53-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzeneacetaldehyde, a-methyl-a-(2-oxopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetaldehyde, a-methyl-a-(2-oxopropyl)-(144632-53-1)
• EPA Substance Registry System: Benzeneacetaldehyde, a-methyl-a-(2-oxopropyl)-(144632-53-1)

Safety Data

• Hazardous Substances Data: 144632-53-1(Hazardous Substances Data)

Upstream product

• 144632-46-2 6-(2-carboxymethyl)pyrrolidin-1-yl-3,5-dimethyl-5-phenyl-1,2-oxazine N-oxide 
• 98-86-2 acetophenone 
• 2802-08-6 (E)-4-(dimethylamino)but-3-en-2-one 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 144632-41-7 N-(2-phenylprop-1-enyl)proline methyl ester 
• 34713-70-7 2-Phenylpropanal 
• 54976-37-3 3-phenylbut-2-en-1-ol 
• 188476-10-0 ((E)-2-Allyloxy-1-methyl-vinyl)-benzene 
• 24401-39-6 2-methyl-2-phenyl-pentenal 
• 171083-61-7 4-methyl-4-phenylhex-5-en-2-one 

Downstream Products

• 36920-29-3 4-methyl-4-phenylcyclopent-2-en-1-one 

Relevant articles and documents

Directed C-C bond cleavage of a cyclopropane intermediate generated from: N -tosylhydrazones and stable enaminones: Expedient synthesis of functionalized 1,4-ketoaldehydes

An efficient method to construct functionalized 1,4-ketoaldehydes bearing all-carbon α-quaternary centers via regioselective C-C bond activation has been described. The cyclopropanation of bench-stable enaminones with in situ generated diazo reagents from

A simple strategy for spirocyclopentannulation of cyclic ketones. Formal total synthesis of (±)-acorone

A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7 via a prochiral precursor constituting a formal total synthesis of (±)-acorone (6), are described.